| Group | 12 | Melting point | 321.069 oC, 609.924 oF, 594.219 K |
| Period | 5 | Boiling point | 767 oC, 1412.6 oF, 1040.15 K |
| Block | d | Density (kg m-3) | 8647 |
| Atomic number | 48 | Relative atomic mass | 112.411 |
| State at room temperature | Solid | Key isotopes | 114Cd |
| Electron configuration | [Kr] 4d105s2 | CAS number | 7440-43-9 |
| ChemSpider ID | 22410 | ChemSpider is a free chemical structure database | |
Image explanation
The alchemical symbol used here was once used to represent “earth” elements. Cadmium is a natural element in the earth's crust.
Appearance
A silvery metal produced as a by-product of zinc refining. It is used in rechargeable batteries, and cadmium sulfide was once a common pigment known as cadmium yellow. Cadmium accumulates in the body; although a person’s daily intake may be as little as 0.05 milligrammes, he or she will have stored on average about 50 milligrammes. Cadmium is a poison and is known to cause birth defects and cancer. As a result, there are moves to limit its use.
Uses
Cadmium is used extensively in electroplating, which accounts for about 60% of its use. It is also used in many types of solder, for standard e.m.f. cells, for nickel-cadmium batteries and in rods to control atomic fission. It is a component of some of the lowest melting alloys, alloys with low coefficients of friction, and alloys with greatresistance to fatigue. Cadmium compounds are used in blue and green phosphors in colour television sets. Cadmium forms a number of compounds, the sulfide being used as an artist’s pigment as it is bright yellow.
Biological role
Cadmium is toxic, carcinogenic and teratogenic and accumulates in the body. In the past, failure to recognise the toxicity of this element caused workers to be exposed to danger in the form of solder fumes and cadmium plating baths.
Natural abundance
The only mineral containing significant quantities of cadmium is greenockite, although some is present in sphalerite. Almost all commercially produced cadmium is obtained as a by-product of the treatment of zinc, copper and lead ores.
| Atomic radius, non-bonded (Å) | 2.180 | Covalent radius (Å) | 1.4 |
| Electron affinity (kJ mol-1) | Not stable |
Electronegativity (Pauling scale) |
1.690 |
|
Ionisation energies (kJ mol-1) |
1st
867.769
2nd
1631.403
3rd
3616.267
4th
-
5th
-
6th
-
7th
-
8th
-
|
||
|
|
| Common oxidation states | 2 | ||||
| Isotopes | Isotope | Atomic mass | Natural abundance (%) | Half life | Mode of decay |
| 106Cd | 105.906 | 1.25 | > 1.9 x 1019 y | EC, EC | |
| 108Cd | 107.904 | 0.89 | > 4.1 x 1017 y | EC EC | |
| 110Cd | 109.903 | 12.49 | - | - | |
| 111Cd | 110.904 | 12.8 | - | - | |
| 112Cd | 111.903 | 24.13 | - | - | |
| 113Cd | 112.904 | 12.22 | 8.04 x 1015 y | β-β- | |
| 114Cd | 113.903 | 28.73 | > 1.3 x 1018 y | β-β- | |
| 116Cd | 115.905 | 7.49 | 3.8 x 1019 y | β-β- | |
| 113In | 112.904 | 4.29 | - | - | |
|
Molar heat capacity (J mol-1 K-1) |
26.02 | Young's modulus (GPa) | 49.9 | |||||||||||
| Shear modulus (GPa) | 19.2 | Bulk modulus (GPa) | 41.6 | |||||||||||
| Vapour pressure | ||||||||||||||
| Temperature (K) |
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| Pressure (Pa) |
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Images: Visual Elements © Murray Robertson 2011
Mining and Sourcing data: British Geological Survey – natural environment research council.
Text: John Emsley Nature’s Building Blocks: An A-Z Guide to the Elements, Oxford University Press, 2nd Edition, 2011.
Data: CRC Handbook of Chemistry and Physics, CRC Press, 92nd Edition, 2011.
G. W. C. Kaye and T. H. Laby Tables of Physical and Chemical Constants, Longman, 16th Edition, 1995.
Members of the RSC can access these books through our library.
Mining and Sourcing data: British Geological Survey – natural environment research council.
Text: John Emsley Nature’s Building Blocks: An A-Z Guide to the Elements, Oxford University Press, 2nd Edition, 2011.
Data: CRC Handbook of Chemistry and Physics, CRC Press, 92nd Edition, 2011.
G. W. C. Kaye and T. H. Laby Tables of Physical and Chemical Constants, Longman, 16th Edition, 1995.
Members of the RSC can access these books through our library.
