| Group | 12 | Melting point | -38.83 oC, -37.894 oF, 234.32 K |
| Period | 6 | Boiling point | 356.62 oC, 673.916 oF, 629.77 K |
| Block | d | Density (kg m-3) | 13546 |
| Atomic number | 80 | Relative atomic mass | 200.59 |
| State at room temperature | Liquid | Key isotopes | 202Hg |
| Electron configuration | [Xe] 4f145d106s2 | CAS number | 7439-97-6 |
| ChemSpider ID | 22373 | ChemSpider is a free chemical structure database | |
Image explanation
This element is a complex metal that has much visual imagery associated with it, but the traditional alchemical symbol is the most iconic. The association with the planet Mercury (and hence astrology) is perhaps where many people will have seen this symbol used before. The dragon or serpent in the background is derived from early alchemical drawings and is often seen in association with the element. Click through to the alchemical symbol for Mercury and other elements.
Appearance
Mercury has fascinated people for millennia, as a heavy liquid metal that can be extracted easily by heating cinnabar, a red ore (mercury sulfide). Mercury is known to be dangerous in all its forms, and use is now confined to industry in the manufacture of chlorine and sodium hydroxide, although even here it is being phased out. Some is still used to treat seed corn to make it resistant to fungus disease, and in street lighting, dental amalgam and electrical apparatus. Older uses - in thermometers, in felt production and as a de-worming powder - have all been superseded. Mercury is widespread in the environment - every mouthful of food we eat contains a little. Our daily intake is about 0.01 milligramme (about a 0.3 grammes in a lifetime), and this we can cope with easily. However, one form of mercury - methylmercury - is particularly dangerous; it can be formed by micro-organisms in polluted waters, absorbed by fish and so eaten by people.
Uses
Mercury easily forms alloys, called amalgams, with other metals such as gold, silver and tin. Its ease in amalgamating with gold is made use of in recovering gold from its ores. It is used in the manufacture of sodium hydroxide and chlorine by electrolysis of brine. The metal is widely used in making advertising signs, mercury switches and other electrical apparatus. It is used in laboratory work for making thermometers, barometers, diffusion pumps and many other instruments. Other uses are in pesticides, dental work, batteries and catalysts. Because of its toxicity, all these uses are being phased out or are under review. Some mercury salts and organic mercury compounds are still important, including mercurous chloride (calomel), which is used in electrolysis, and mercuric sulfide (wermilion), a high-grade paint pigment.
Biological role
Mercury has no known biological role. It is a virulent poison, readily absorbed through the respiratory tract, the
gastrointestinal tract or through the skin. It is a cumulative poison and dangerous levels are readily attained in air. It
is now always handled with the utmost care.
Natural abundance
Mercury occurs very rarely free in nature, but can be found in ores, principally cinnabar. This is mostly found in Spain and Italy, which together produce about 50% of the world’s supply of this element. The metal is obtained by heating cinnabar in a current of air and condensing the vapour.
| Atomic radius, non-bonded (Å) | 2.230 | Covalent radius (Å) | 1.32 |
| Electron affinity (kJ mol-1) | Not stable |
Electronegativity (Pauling scale) |
1.900 |
|
Ionisation energies (kJ mol-1) |
1st
1007.065
2nd
1809.755
3rd
3299.796
4th
-
5th
-
6th
-
7th
-
8th
-
|
||
|
|
| Common oxidation states | 2, 1 | ||||
| Isotopes | Isotope | Atomic mass | Natural abundance (%) | Half life | Mode of decay |
| 196Hg | 195.966 | 0.15 | > 2.5 x 1018 y | α | |
| 198Hg | 197.967 | 9.97 | - | - | |
| 199Hg | 198.968 | 16.87 | - | - | |
| 200Hg | 199.968 | 23.1 | - | - | |
| 201Hg | 200.97 | 13.18 | - | - | |
| 202Hg | 201.971 | 29.86 | - | - | |
| 204Hg | 203.973 | 6.87 | - | - | |
|
Molar heat capacity (J mol-1 K-1) |
27.983 | Young's modulus (GPa) | Unknown | |||||||||||
| Shear modulus (GPa) | Unknown | Bulk modulus (GPa) | 25 | |||||||||||
| Vapour pressure | ||||||||||||||
| Temperature (K) |
|
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| Pressure (Pa) |
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Images: Visual Elements © Murray Robertson 2011
Mining and Sourcing data: British Geological Survey – natural environment research council.
Text: John Emsley Nature’s Building Blocks: An A-Z Guide to the Elements, Oxford University Press, 2nd Edition, 2011.
Data: CRC Handbook of Chemistry and Physics, CRC Press, 92nd Edition, 2011.
G. W. C. Kaye and T. H. Laby Tables of Physical and Chemical Constants, Longman, 16th Edition, 1995.
Members of the RSC can access these books through our library.
Mining and Sourcing data: British Geological Survey – natural environment research council.
Text: John Emsley Nature’s Building Blocks: An A-Z Guide to the Elements, Oxford University Press, 2nd Edition, 2011.
Data: CRC Handbook of Chemistry and Physics, CRC Press, 92nd Edition, 2011.
G. W. C. Kaye and T. H. Laby Tables of Physical and Chemical Constants, Longman, 16th Edition, 1995.
Members of the RSC can access these books through our library.
