| Discovery date | 1861 |
| Discovered by | W. Crookes |
| Origin of the name | Thallium is derived from the Greek 'thallos', meaning a green twig. |
| Allotropes |
|
| Group | 13 | Melting point | 304 oC, 579.2 oF, 577.15 K |
| Period | 6 | Boiling point | 1473 oC, 2683.4 oF, 1746.15 K |
| Block | p | Density (kg m-3) | 11871 |
| Atomic number | 81 | Relative atomic mass | 204.383 |
| State at room temperature | Solid | Key isotopes | 205Tl |
| Electron configuration | [Xe] 4f145d106s26p1 | CAS number | 7440-28-0 |
| ChemSpider ID | 4514293 | ChemSpider is a free chemical structure database | |
| Atomic radius, non-bonded (Å) | 1.960 | Covalent radius (Å) | 1.44 |
| Electron affinity (kJ mol-1) | 36.375 |
Electronegativity (Pauling scale) |
1.800 |
|
Ionisation energies (kJ mol-1) |
1st
589.351
2nd
1971.030
3rd
2878.155
4th
-
5th
-
6th
-
7th
-
8th
-
|
||
|
|
| Common oxidation states | 3, 1 | ||||
| Isotopes | Isotope | Atomic mass | Natural abundance (%) | Half life | Mode of decay |
| 203Tl | 202.972 | 29.52 | - | - | |
| 205Tl | 204.974 | 70.48 | - | - | |
|
Molar heat capacity (J mol-1 K-1) |
26.32 | Young's modulus (GPa) | Unknown | |||||||||||
| Shear modulus (GPa) | Unknown | Bulk modulus (GPa) | 43 | |||||||||||
| Vapour pressure | ||||||||||||||
| Temperature (K) |
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| Pressure (Pa) |
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The discovery of thallium was controversial. William Crookes of the Royal College of Science in London was the first to observe a green line in the spectrum of some impure sulfuric acid, and realised that it meant a new element. He announced his discovery in March 1861 in Chemical News. However, he did very little research into it.
Meanwhile, in 1862, Claude-August Lamy of Lille, France, began to research thallium more thoroughly and even cast a small ingot of the metal itself. The French Academy now credited him its discovery. He sent the ingot to the London International Exhibition of 1862, where it was acclaimed as a new metal and he was awarded a medal. Crookes was furious and so the exhibition committee awarded him a medal as well.
| Listen to Thallium Podcast |
|
Transcript :
Chemistry in Its Element - Thallium(Promo) You're listening to Chemistry in its element brought to you by Chemistry World, the magazine of the Royal Society of Chemistry (End promo) Chris Smith Hello, this week's element sees us immersed in a murder mystery - Henry Nicholls: Henry Nicholls During World War I, Agatha Christie worked in a hospital and then a pharmacy, an experience that could explain the presence of poisons in many of her plots. In The Pale Horse, a thriller published in 1961, the star of the show was thallium, also known as "the poisoner's poison" because many salts of this soft, silvery metal is soluble in water, producing a colourless, odourless and tasteless liquid with a delayed effect on the victim. Here's an excerpt from the dramatic climax in which the novel's narrator Mark Easterbrook solves the mystery of several unexplained deaths. I slammed back the receiver, then took it off again. I dialed a number and was lucky enough this time to get Lejeune straight away. "Listen," I said, "is Ginger's hair coming out by the roots in handfuls?" "Well - as a matter of fact I believe it is. High fever, I suppose." "Fever my foot," I said. "What Ginger's suffering from, what they've all suffered from, is thallium poisoning. Please God, may we be in time..." Christie may have got the idea for her plot a few years' earlier in 1957, when the KGB attempted to assassinate Nikolai Khokhlov, a former KGB assassin himself who had defected to the United States. In turn Christie's dramatic and detailed description of the symptoms of thallium poisoning in The Pale Horse is thought to have saved at least two lives and led to the arrest and conviction of a British factory worker who had used thallium to kill his stepmother, two work colleagues and nauseate around 70 others. It is so dangerous because thallium has similar biological properties to potassium ions, hijacking the ubiquitous sodium/potassium membrane pump to smuggle itself into cells throughout the body interfering with the important roles played by potassium. Thallium is pretty abundant in the earth's crust, found in several selenium-containing minerals. Indeed, it was whilst cooking up one such compound in 1861 that British chemist William Crookes noted that "suddenly a bright green line flashed into view and quickly disappeared." He knew he was onto a new element and called it thallium after the Greek for green shoot or twig - thallos. The following year, he succeeded in isolating small quantities of the element, but nowhere near the quantities obtained by French chemist Claude-Auguste Lamy who was working away independently with a greater bulk of raw material. When, in 1862, Lamy was awarded a medal at the International Exhibition in London For the discovery of a new and abundant source of thallium, Crookes had a fit and it was only with his election to the Royal Society in 1863 - largely on the back of his thallium work - that the cross-channel spat for priority died down. Subsequent work on the chemistry of thallium showed it to have similar properties to several other elements, including silver, mercury and lead. So much so that French chemist Jean-Baptiste Dumas later dubbed it the "ornithorhyncus, or duck-billed platypus of the metals." The raw material on which both Crookes and Lamy worked came from waste products deposited during the manufacture of sulphuric acid. The commercial production of thallium today is not dissimilar, with the metal mostly recovered as a by-product of smelting iron, zinc or lead sulphides to make sulphur dioxide. The resulting thallium contains the two naturally occurring stable isotopes, with around 30% of it made up of atomic mass 203 and the remaining 70% comprised of atomic mass 205. Owing to its toxic properties, thallium has been used as a rodenticide, though there are safer ways to kill rats and the use of this chemical in the environment is now banned in many countries. Today, thallium is of greatest use to the electronics industry. In particular, the conductivity of thallium sulphide alters on exposure to infrared light, making it an important compound in photocells. Thallium bromide-iodide crystals have also been used in infrared detectors. The addition of metals like thallium to glass can also reduce its melting point to as low as 150 degrees centigrade. As such low-melting point glasses do not shatter like normal glasses, they are particularly useful for the manufacture of electronic parts. Thallium is also being tested in high-temperature ceramic superconductors. Alongside the two stable isotopes, there are a further 23 radioisotopes, though most of them with fleeting half lives. One of them, thallium 201, is useful in nuclear medicine. Its injected into the bloodstream and will find its way into all tissues with the help of the sodium/potassium membrane pump. This can then reveal to the clinician any part of the body not bathed in blood or where the membrane transporter is not working properly. In particular, it is used to image the blood flow to heart muscle in patients suspected of coronary artery disease. Thankfully, with a suitably short half-life of just 72.5 hours, Thallium 201 disappears from the body long before it can cause the lethal damage of the more stable isotopes. In The Pale Horse, Agatha Christie was not as explicit about the treatment for thallium poisoning as she was about its symptoms. "Do they know how to treat thallium poisoning?" asks the narrator Mark Easterbrook when he reaches the hospital where the hair-shedding Ginger has been taken. "You don't often get a case of it," the investigating officer Inspector Lejeune tells him. "But everything possible will be tried." It was, and for those who like their happy endings you'll be pleased to know that Ginger makes a full recovery from the thallium poisoning that had stricken her down.
Chris Smith That's a relief, she was OK, although you've totally blown the ending Henry! That was science writer Henry Nicholls with the story of Thallium. Next time, to the element that suits someone who doesn't want to blow up the world, maybe just a small bit of it. Brian Clegg When it comes to practical uses, this silvery substance is an excellent neutron emitter. This makes it handy for kick-starting nuclear reactors, where a high neutron flow is required to get the chain reaction going. It also means that, in principle, californium would make effective small scale nuclear weapons, requiring as little as five kilograms of californium 251 to achieve critical mass - about half the amount of plutonium required for a bomb. Chris Smith That's the story of Californium, which apart from its use potentially as a nuclear weapon is also useful for finding gold and striking oil. And you can join us on next week's Chemistry in its Element to find out how. I'm Chris Smith, thank you for listening and goodbye! Chemistry in its elementis brought to you by the Royal Society of Chemistry and produced by thenakedscientists dot com. There's more information and other episodes of Chemistry in its element on our website at chemistryworld dot org forward slash elements. (End promo) |
Mining and Sourcing data: British Geological Survey – natural environment research council.
Text: John Emsley Nature’s Building Blocks: An A-Z Guide to the Elements, Oxford University Press, 2nd Edition, 2011.
Additional information for platinum, gold, neodymium and dysprosium obtained from Material Value Consultancy Ltd www.matvalue.com
Data: CRC Handbook of Chemistry and Physics, CRC Press, 92nd Edition, 2011.
G. W. C. Kaye and T. H. Laby Tables of Physical and Chemical Constants, Longman, 16th Edition, 1995.
Members of the RSC can access these books through our library.