Synthesis and Characterization of the Homobimetallic [Bis(2-hydroxy-1-naphthaldehyde) oxaloyldihydrazonato]bisdioxomolybdenum(VI) Tetrahydrate Complex and its Reactivity towards Proton and Electron Donor Reagents
Abstract
The homobimetallic molybdenum(VI)
complexes
[(MoO
2
)
2
(napoxlh)]·4H
2
O
1,
[{(µ
2
-O)MoO
2
}MoO
2
(napoxl
hH
2
)]·2L·4H
2
O, [L=pyridine
(py) 2, 3-pic 3] and the molybdenum(V) complexes
[MoO
2
(napoxlh)(sylsh)
2
]·5H
2
O 4 and [Mo
2
(napoxlh)(inh)
2
(H
2
O)
2
]·3H
2
O 5, (3-pic=3-picoline,
sylshH
3
=salicyloylhydrazine and
inhH
3
=isonicotinoylhydrazine) are synthesized from
bis(2-hydroxy-1-naphthaldehyde) oxaloyldihydrazone
(napoxlhH
4
) and then characterized.
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