The electronic structure of uncapped trinuclear clusters of early transition metals with six µ2 bridging and three terminal arene ligands (η5, η6) has been analysed, a triplet ground state being predicted for the recently synthesized cluster ion [(η5-C5Me5)3Re3(µ2-O)6]2+, at variance with the reported interpretation of n.m.r. data, which indicates diamagnetism.
P. Hofmann and N. Rösch, J. Chem. Soc., Chem. Commun., 1986, 843 DOI: 10.1039/C39860000843
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