Issue 20, 1989

Krypton bis[pentafluoro-oxotellurate(VI)], Kr(OTeF5)2, the first example of a Kr–O bond

Abstract

Krypton bis[pentafluoro-oxotellurate(VI)] provides the first example of a species containing a krypton–oxygen bond and has been prepared by the reaction of KrF2 with natural abundance and 17O-enriched B(OTeF5)3 at –90 to –112 °C in SO2CIF solvent; characterization of the thermally unstable Kr(OTeF5)2 and its decomposition products has been achieved using 19F and 17O n.m.r. spectroscopy.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 1576-1578

Krypton bis[pentafluoro-oxotellurate(VI)], Kr(OTeF5)2, the first example of a Kr–O bond

J. C. P. Sanders and G. J. Schrobilgen, J. Chem. Soc., Chem. Commun., 1989, 1576 DOI: 10.1039/C39890001576

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