Issue 11, 2000
From the journal:

Chemical Communications

A dinuclear iron(iii) complex with a bridging urea anion: implications for the urease mechanismElectronic supplementary information (ESI) available: selected data for 2 kinetic data and rotatable 3-D crystal structure diagram in CHIME format. See http://www.rsc.org/suppdata/cc/b0/b000286k/

Sergey V. Kryatov,a   Alexander Y. Nazarenko,b   Paul D. Robinsonc  and  Elena V. Rybak-Akimova*a  

* Corresponding authors

a Department of Chemistry, Tufts University, Medford, Massachusetts, USA.
E-mail: erybakak@emerald.tufts.edu

b Department of Chemistry and Biochemistry, Southern Illinois University, Carbondale, Illinois, USA

c Department of Geology, Southern Illinois University, Carbondale, Illinois, USA

Abstract

A novel complex [FeIII2(μ-O){μ-OC(NH2)NH} (tpa)2](ClO4)3 [tpa = tris(2-pyridylmethyl)amine] has been synthesized and fully characterized; its formation from urea and the [FeIII2(μ-O)(tpa)2(OH)(H2O) ]3+ precursor in aqueous acetonitrile is a reversible multistep process.

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Supplementary files

Article information

DOI
https://doi.org/10.1039/B000286K
Article type
Communication
Submitted
05 Jan 2000
Accepted
18 Apr 2000
First published
16 May 2000

Chem. Commun., 2000, 921-922

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A dinuclear iron(III) complex with a bridging urea anion: implications for the urease mechanism

S. V. Kryatov, A. Y. Nazarenko, P. D. Robinson and E. V. Rybak-Akimova, Chem. Commun., 2000, 921 DOI: 10.1039/B000286K

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