Photolysis of Al, Ga or In atoms (M) isolated in NH3-doped Ar matrices gives first the divalent amido derivative HMNH2 (λ = 436 nm) and then the univalent and trivalent amido derivatives MNH2 and H2MNH2 (λ = 200–800 nm); the measured and calculated properties of H2MNH2 are outlined.
Amidoalane, amidogallane and amidoindane, H2MNH2 (M = Al, Ga or In): a matrix study of three prototypal molecules with the potential for M–N multiple bonding
H. Himmel, A. J. Downs and T. M. Greene, Chem. Commun., 2000, 871 DOI: 10.1039/B001652G
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