Issue 29, 2005
From the journal:

Chemical Communications

Syntheses and structures of mono-, di- and tetranuclear rhodium or iridium complexes of thiacalix[4]arene derivatives†

Kenji Hirata,a   Toshiaki Suzuki,‡a   Ai Noya,a   Izuru Takeia  and  Masanobu Hidai*a  

* Corresponding authors

a Department of Materials Science and Technology, Faculty of Industrial Science and Technology, Tokyo University of Science, Noda, Chiba, Japan
E-mail: hidai@rs.noda.tus.ac.jp
Fax: +81 4 7123 9362
Tel: +81 4 7124 1501

Abstract

The reactions of [Cp*MCl2]2 (Cp* = η5-C5Me5, M = Rh, Ir) with thiacalix[4]arene (TC4A(OH)4) and tetramercaptothiacalix[4]arene (TC4A(SH)4) gave the mononuclear complexes [(Cp*M){η3-TC4A(OH)2(O)2}] and the dinuclear complexes [(Cp*M)2{η3∶η3-TC4A(S)4}] respectively, while the analogous reactions with dimercaptothiacalix[4]arene (TC4A(OH)2(SH)2) produced the tetranuclear complexes [(Cp*M)2(Cp*MCl2)2-{η3∶η3∶η1∶η1-TC4A(O)2(S)2}].

Graphical abstract: Syntheses and structures of mono-, di- and tetranuclear rhodium or iridium complexes of thiacalix[4]arene derivatives

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Article information

DOI
https://doi.org/10.1039/B502999F
Article type
Communication
Submitted
03 Mar 2005
Accepted
27 May 2005
First published
15 Jun 2005

Chem. Commun., 2005, 3718-3720

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Syntheses and structures of mono-, di- and tetranuclear rhodium or iridium complexes of thiacalix[4]arene derivatives

K. Hirata, T. Suzuki, A. Noya, I. Takei and M. Hidai, Chem. Commun., 2005, 3718 DOI: 10.1039/B502999F

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