Issue 12, 2006
From the journal:

Chemical Communications

Synthesis of Ru–Pt and Ru–Pd mixed-metal imido clusters from a diruthenium imido-methylene scaffold [(Cp*Ru)2(μ2-NPh)(μ2-CH2)]†

Shin Takemoto,a   Hidenobu Morita,a   Ken Kamikawaa  and  Hiroyuki Matsuzaka*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Gakuen cho 1-1, Sakai, Japan
E-mail: matuzaka@c.s.osakafu-u.ac.jp
Fax: 81-72-254-9931
Tel: 81-72-254-9696

Abstract

The diruthenium μ2-imido μ2-methylene complex [(Cp*Ru)2(μ2-NPh)(μ2-CH2)] serves as a bifunctional scaffold for cluster synthesis, producing a μ3-imido Ru2Pt cluster [(Cp*Ru)2(μ3-NPh)(μ2-CH2)Pt(PMe3)2] on treatment with [Pt(η2-C2H4)(PMe3)2] and a μ3-methylidyne Ru4Pd2 cluster [(Cp*Ru)2(μ2-NPh)(μ3-CH)PdCl]2 with [PdMeCl(cod)].

Graphical abstract: Synthesis of Ru–Pt and Ru–Pd mixed-metal imido clusters from a diruthenium imido-methylene scaffold [(Cp*Ru)2(μ2-NPh)(μ2-CH2)]

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Article information

DOI
https://doi.org/10.1039/B517222E
Article type
Communication
Submitted
05 Dec 2005
Accepted
25 Jan 2006
First published
16 Feb 2006

Chem. Commun., 2006, 1328-1330

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Synthesis of Ru–Pt and Ru–Pd mixed-metal imido clusters from a diruthenium imido-methylene scaffold [(Cp*Ru)2(μ2-NPh)(μ2-CH2)]

S. Takemoto, H. Morita, K. Kamikawa and H. Matsuzaka, Chem. Commun., 2006, 1328 DOI: 10.1039/B517222E

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