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Chem. Commun., 2007, 1510 - 1511, DOI: 10.1039/b616685g

A bimetallic N-heterocyclic carbene complex featuring a short Cr–Cr distance

Kevin A. Kreisel, Glenn P. A. Yap and Klaus H. Theopold

The alkylation of a chelating bis(carbene) complex of CrCl2 yields an unusual bimetallic complex featuring a short Cr–Cr distance, novel ligand coordination, and CH3 ligand exchange.

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