Issue 28, 2007

Enhanced selectivity in the conversion of methanol to 2,2,3-trimethylbutane (triptane) over zinc iodide by added phosphorous or hypophosphorous acid

Abstract

The yield of triptane from the reaction of methanol with zinc iodide is dramatically increased by addition of phosphorous or hypophosphorous acid, via transfer of hydride from a P–H bond to carbocationic intermediates.

Graphical abstract: Enhanced selectivity in the conversion of methanol to 2,2,3-trimethylbutane (triptane) over zinc iodide by added phosphorous or hypophosphorous acid

Supplementary files

Article information

Article type
Communication
Submitted
11 Apr 2007
Accepted
06 Jun 2007
First published
20 Jun 2007

Chem. Commun., 2007, 2974-2976

Enhanced selectivity in the conversion of methanol to 2,2,3-trimethylbutane (triptane) over zinc iodide by added phosphorous or hypophosphorous acid

J. E. Bercaw, R. H. Grubbs, N. Hazari, J. A. Labinger and X. Li, Chem. Commun., 2007, 2974 DOI: 10.1039/B705470J

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