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Communication

Chem. Commun., 2008, 1563 - 1565, DOI: 10.1039/b719559a

Regioselective 12CO/13CO exchange activity of a mixed-valent Fe(II)Fe(I) model of the Hox state of [FeFe]-hydrogenase

Christine M. Thomas, Tianbiao Liu, Michael B. Hall and Marcetta Y. Darensbourg

A mixed-valent Fe(II)Fe(I) model of the Hox state of [FeFe]-hydrogenase is shown, under certain conditions, to exhibit regioselective 12CO/13CO exchange activity similar to that observed for Hox.

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