Issue 23, 2008
From the journal:

Chemical Communications

Synthesis of bis(σ-aryl)dirhodium(iii) caprolactamates by oxidative arylation with arylboronic acids†‡

Jian-Hua Xie,a   Jason M. Nichols,a   Conrad Lubeka  and  Michael P. Doyle*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Maryland, College Park, USA
E-mail: mdoyle3@umd.edu
Fax: +1 301-314-2779
Tel: +1 301-405-8388

Abstract

Recently discovered stable bis(σ-phenyl)dirhodium(III) caprolactamate and its substituted derivatives are conveniently prepared in high yields from dirhodium(II) caprolactamate and commercially available arylboronic acids in a copper-catalyzed process.

Graphical abstract: Synthesis of bis(σ-aryl)dirhodium(iii) caprolactamates by oxidative arylation with arylboronic acids

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Article information

DOI
https://doi.org/10.1039/B806283H
Article type
Communication
Submitted
14 Apr 2008
Accepted
25 Apr 2008
First published
14 May 2008

Chem. Commun., 2008, 2671-2673

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Synthesis of bis(σ-aryl)dirhodium(III) caprolactamates by oxidative arylation with arylboronic acids

J. Xie, J. M. Nichols, C. Lubek and M. P. Doyle, Chem. Commun., 2008, 2671 DOI: 10.1039/B806283H

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