Issue 2, 2009
From the journal:

Chemical Communications

A new type of iodosulfite ion formulated as I2SO22−†‡

Isoroku Nagasawa,*a   Hideaki Amitaa  and  Hiroshi Kitagawabc  

* Corresponding authors

a Department of Chemistry, Fukuoka University of Education, Akamabunnkyo-machi 1-1, Munakata, Fukuoka, Japan
E-mail: isoroku@fukuoka-edu.ac.jp
Fax: +81 940 351711
Tel: +81 940 351368

b Department of Chemistry, Faculty of Science, Kyushu University, Hakozaki 6-10-1, Higashi-ku, Fukuoka 812-8581, Japan
E-mail: kitagawa@chem.kyushu-univ.jp
Fax: +81 92 642 2319
Tel: +81 92 642 2319

c JST CREST, Sanbancho 5, Chiyoda-ku, Tokyo 102-0075, Japan

Abstract

This paper deals with a notable halosulfite ion, (I2SO22−), which is a rare example of this inorganic anion species; the reaction of the platinum(II) complex, [Pt(depe)2]I2 with SO2 afforded the complex, [Pt(depe)2](I2SO2) containing the rare anion; considering with the VSEPR concept, the structure of the anion could be interpreted as a distorted trigonal bipyramid.

Graphical abstract: A new type of iodosulfite ion formulated as I2SO22−

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Article information

DOI
https://doi.org/10.1039/B815809F
Article type
Communication
Submitted
09 Sep 2008
Accepted
28 Oct 2008
First published
13 Nov 2008

Chem. Commun., 2009, 204-205

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A new type of iodosulfite ion formulated as I2SO22−

I. Nagasawa, H. Amita and H. Kitagawa, Chem. Commun., 2009, 204 DOI: 10.1039/B815809F

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