Issue 23, 2009
From the journal:

Chemical Communications

A three-dimensional adamantane-like nanoscopic cage built from four iodide-bridged triangular Mo3S7cluster units†

Larry R. Falvello,a   Rosa Llusar,*b   Sonia Triguerob  and  Cristian Vicent*c  

* Corresponding authors

a Departamento de Química Inorgánica and I.C.M.A, Universidad de Zaragoza-C.S.I.C, Spain
Fax: +34-976 76118

b Departament de Química Física i Analítica, Universitat Jaume I, Av. Sos Baynat s/n, Castello, Spain
E-mail: Rosa.Llusar@qfa.uji.es

c Serveis Centrals d’Instrumentació Científica, Universitat Jaume I, Av. Sos Baynat s/n, Castelló, Spain
E-mail: barrera@sg.uji.es

Abstract

Chemical oxidation of a Mo3S7cluster featuring catecholate ligands, namely [Mo3S7(Cl4cat)3]2− (Cl4cat = tetrachlorocatecholate), allows the isolation of a unique nanoscopic molecular cage made of four iodide-bridged Mo3S7clusters as the kinetically favoured product.

Graphical abstract: A three-dimensional adamantane-like nanoscopic cage built from four iodide-bridged triangular Mo3S7cluster units

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B823223G
Article type
Communication
Submitted
24 Dec 2008
Accepted
30 Mar 2009
First published
05 May 2009

Chem. Commun., 2009, 3440-3442

Permissions

Request permissions

A three-dimensional adamantane-like nanoscopic cage built from four iodide-bridged triangular Mo3S7cluster units

L. R. Falvello, R. Llusar, S. Triguero and C. Vicent, Chem. Commun., 2009, 3440 DOI: 10.1039/B823223G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements