Issue 8, 2010
From the journal:

Chemical Communications

Organocuprate(iii) chemistry: synthesis and reactivity of amido, cyano, phosphido and thiolato ate complexes of copper(iii)

Steven H. Bertz,*a   Michael D. Murphy,b   Craig A. Ogle*b  and  Andy A. Thomasb  

* Corresponding authors

a Complexity Study Center, Mendham, USA
E-mail: sbertz@complexitystudycenter.org

b Department of Chemistry, University of North Carolina–Charlotte, Charlotte, USA
E-mail: cogle@uncc.edu
Fax: +1 704-687-3151
Tel: +1 704-687-2524

Abstract

Lithium tetramethylcuprate(III) 1 reacts readily at −100 °C with appropriate sources of H+ or X+ (X = Br, I) to remove a methyl and in some cases incorporate the counterion (e.g., arylthio or cyano) to give stable complexes. These derivatives can in turn serve as starting materials for other CuIII complexes.

Graphical abstract: Organocuprate(iii) chemistry: synthesis and reactivity of amido, cyano, phosphido and thiolato ate complexes of copper(iii)

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Article information

DOI
https://doi.org/10.1039/B921412G
Article type
Communication
Submitted
13 Oct 2009
Accepted
10 Dec 2009
First published
25 Jan 2010

Chem. Commun., 2010,46, 1255-1256

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Organocuprate(III) chemistry: synthesis and reactivity of amido, cyano, phosphido and thiolato ate complexes of copper(III)

S. H. Bertz, M. D. Murphy, C. A. Ogle and A. A. Thomas, Chem. Commun., 2010, 46, 1255 DOI: 10.1039/B921412G

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