Issue 21, 2000
From the journal:

CrystEngComm

Solvent mediated disruption of intermolecular association in phosphinegold(I) thiolates: the relative importance of carboxylic acid dimer formation on crystal structure

Douglas R. Smyth,   Beverly R. Vincent  and  Edward R. T. Tiekink  

Abstract

The crystal and molecular structures of [Au2(2-Hmba)2(-PPh2(CH2)2Ph2P)] (1) and its 1 : 2 adduct with DMSO (1.2DMSO) are reported. In 1, a two-dimensional structure is found mediated, in part, by carboxylic acid dimer formation within the layers. In the di-solvate, these functionalities are not available as they are involved in hydrogen-bonding contacts to DMSO. Nevertheless, a two-dimensional structure is also formed showing that carboxylic acid dimer formation is not pivotal in determining the crystal structure in these systems

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Article information

DOI
https://doi.org/10.1039/B004742M
Article type
Paper

CrystEngComm, 2000,2, 115-120

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Solvent mediated disruption of intermolecular association in phosphinegold(I) thiolates: the relative importance of carboxylic acid dimer formation on crystal structure

D. R. Smyth, B. R. Vincent and E. R. T. Tiekink, CrystEngComm, 2000, 2, 115 DOI: 10.1039/B004742M

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