Issue 10, 2009
From the journal:

CrystEngComm

Fe(II) spincrossover complex of [1,2,5]thiadiazolo[3,4-f][1,10]phenanthroline†

Yoshiaki Shuku,a   Rie Suizu,a   Kunio Awaga*a  and  Osamu Satob  

* Corresponding authors

a Research Center for Materials Science & Department of Chemistry, Nagoya University, Furo-cho, Chikusa, Nagoya, Japan
E-mail: awaga@mbox.chem.nagoya-u.ac.jp
Fax: +81-52-789-2484
Tel: +81-52-789-2487

b Institute of Materials Chemistry and Engineering, Kyushu University, 6-1 Kasuga, Fukuoka, Japan

Abstract

We prepared an iron(II) spin crossover complex with a new ligand, [1,2,5]thiadiazolo[3,4-f][1,10]phenanthroline, which is a 1,10-phenanthroline analogue annulated with a thiadiazole moiety. X-Ray crystal analysis indicated a 3D network structure formed by short S⋯S contacts, and magnetic measurements revealed a broad transition above room temperature.

Graphical abstract: Fe(II) spincrossover complex of [1,2,5]thiadiazolo[3,4-f][1,10]phenanthroline

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Article information

DOI
https://doi.org/10.1039/B906845G
Article type
Paper
Submitted
06 Apr 2009
Accepted
26 May 2009
First published
11 Jun 2009

CrystEngComm, 2009,11, 2065-2068

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Fe(II) spincrossover complex of [1,2,5]thiadiazolo[3,4-f][1,10]phenanthroline

Y. Shuku, R. Suizu, K. Awaga and O. Sato, CrystEngComm, 2009, 11, 2065 DOI: 10.1039/B906845G

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