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CrystEngComm

Design and understanding of solid-state and crystalline materials




Paper

CrystEngComm, 2009, 11, 2065 - 2068, DOI: 10.1039/b906845g


Fe(II) spincrossover complex of [1,2,5]thiadiazolo[3,4-f][1,10]phenanthroline

Yoshiaki Shuku, Rie Suizu, Kunio Awaga and Osamu Sato


We prepared an iron(II) spin crossover complex with a new ligand, [1,2,5]thiadiazolo[3,4-f][1,10]phenanthroline, which is a 1,10-phenanthroline analogue annulated with a thiadiazole moiety. X-Ray crystal analysis indicated a 3D network structure formed by short SS contacts, and magnetic measurements revealed a broad transition above room temperature.

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