Issue 15, 2000
From the journal:

Physical Chemistry Chemical Physics

The structure of ethylbenzene as a solute in liquid crystalline solvents [italic v (to differentiate from Times ital nu)]ia analysis of proton NMR spectra

Catia Algieri,a   Franca Castiglione,a   Giorgio Celebre,a   Giuseppina De Luca,a   Marcello Longeri*a  and  James W. Emsleyb  

* Corresponding authors

a Dipartimento di Chimica, Uniersità della Calabria, Arcaacata di Rende (Cs), Italy

b Department of Chemistry, Uniersity of Southampton, Southampton, UK

Abstract

Previous attempts to analyze the proton spectrum of ethylbenzene as a solute in nematic liquid crystalline solvents failed, but a successful strategy has now been devised and is described here. The proton spectra of samples of ethylbenzene dissolved in four different liquid crystals have been analyzed to yield sets of the partially-averaged dipolar couplings, Dij. The couplings are then used to test models for the structure and conformation of this molecule.

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Article information

DOI
https://doi.org/10.1039/B002803G
Article type
Paper
Submitted
07 Apr 2000
Accepted
07 Jun 2000
First published
03 Jul 2000

Phys. Chem. Chem. Phys., 2000,2, 3405-3413

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The structure of ethylbenzene as a solute in liquid crystalline solvents [italic v (to differentiate from Times ital nu)]ia analysis of proton NMR spectra

C. Algieri, F. Castiglione, G. Celebre, G. De Luca, M. Longeri and J. W. Emsley, Phys. Chem. Chem. Phys., 2000, 2, 3405 DOI: 10.1039/B002803G

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