Issue 23, 1993
From the journal:

Journal of the Chemical Society, Dalton Transactions

Occurrence of a manganese(III) intermediate in the [MnO4]––SO2 redox reaction

Chaitali Bhattacharjee,   Mihir K. Chaudhuri,   Gagan C. Mandal,   Pradip C. Paul  and  Pendyala Srinivas  

Abstract

Evidence for a manganese(III) intermediate, previously implicated in the [MnO4]––SO2 electron-transfer process, has been obtained by conducting the reaction in the presence of F–. A combination of in situ EPR and electronic absorption spectroscopies was used to follow the reaction course and physico-chemical techniques were used to ascertain the identity of the isolated manganese(III) products. The evidence suggests that in the presence of F– manganese(VII) is directly reduced to manganese(III) and thence to manganese(II).

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Article information

DOI
https://doi.org/10.1039/DT9930003497
Article type
Paper

J. Chem. Soc., Dalton Trans., 1993, 3497-3498

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Occurrence of a manganese(III) intermediate in the [MnO4]––SO2 redox reaction

C. Bhattacharjee, M. K. Chaudhuri, G. C. Mandal, P. C. Paul and P. Srinivas, J. Chem. Soc., Dalton Trans., 1993, 3497 DOI: 10.1039/DT9930003497

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