Issue 0, 1974
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Thermal decomposition of dibenz[b,d]iodolium and 10H-dibenz[b,e]-iodininium halides. Evidence for a homolytic pathway from halogen scrambling, hydrogen transfer, and trapping

Takeo Sato,   Kuniaki Shimizu  and  Hiroshi Moriya  

Abstract

The thermal decomposition of dibenz[b,d]iodolium halides and 10H-dibenz[b,e]iodininium halides has been examined. Observation of products of halogen scrambling and hydrogen transfer suggested a radical mechanism involving 2′-iodobiphenyl-2-yl and 2-(2-iodobenzyl)phenyl radicals. Results of trapping experiments with an acetylenic ester suggested the involvment of a biphenyl diradical.

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Article information

DOI
https://doi.org/10.1039/P19740001537
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1974, 1537-1539

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Thermal decomposition of dibenz[b,d]iodolium and 10H-dibenz[b,e]-iodininium halides. Evidence for a homolytic pathway from halogen scrambling, hydrogen transfer, and trapping

T. Sato, K. Shimizu and H. Moriya, J. Chem. Soc., Perkin Trans. 1, 1974, 1537 DOI: 10.1039/P19740001537

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