A short and stereocontrolled synthesis of methyl (12S,5Z,8E,10E)-12-hydroxyheptadeca-5,8,10-trienoate (1), based on a Pd0–TlOH catalysed coupling reaction of the vinyl iodide (3) and the vinylborane (4) is described.
K. C. Nicolaou, N. A. Stylianides and J. Y. Ramphal, J. Chem. Soc., Perkin Trans. 1, 1989, 2131 DOI: 10.1039/P19890002131
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