Issue 8, 1974
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Reactions of potassium carbonyl(π-cyclopentadienyl)nickelate with butenyl and cyclopropylmethyl halides

John M. Brown,   John A. Conneely  and  Konstantinos Mertis  

Abstract

The reaction of carbonyl(π-cyclopentadienyl)nickel anion with but-3-enyl and cyclopropylmethyl halides has been investigated. In the former case, the only isolated product is 1–3-η-but-2-enyl-π-cyclopentadienylnickel (85 : 15 (trans : cis) whereas in the latter, a cyclopropylmethylnickel complex could be isolated. This was converted by thermolysis, or more effectively by photolysis into a 1-σ : 4–5-η-1-oxopent-4-enylnickel, most probably derived by insertion of a cyclopropane C–C bond into the metal carbonyl system.

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Article information

DOI
https://doi.org/10.1039/P29740000905
Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1974, 905-907

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Reactions of potassium carbonyl(π-cyclopentadienyl)nickelate with butenyl and cyclopropylmethyl halides

J. M. Brown, J. A. Conneely and K. Mertis, J. Chem. Soc., Perkin Trans. 2, 1974, 905 DOI: 10.1039/P29740000905

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