Issue 1, 1997
From the journal:

Chemical Communications

Solvent directed aggregation of a metallocene; structures of {[Pb(η-C5H5)2]3 ·C6H5Me}∞ and [Pb(η-C5H5)2]6

Michael A. Beswick,   Catherine Lopez-Casideo,   Michael A. Paver,   Paul R. Raithby,   Christopher A. Russell,   Alexander Steiner  and  Dominic S. Wright  

Abstract

The classic zigzagged chain structure of orthorhombic plumbocene, [Pb(η-C 5 H 5 ) 2 ] ∞ , is obtained by crystal growth from the vapour phase; however, crystallisation from toluene results in modification of the conformation of the polymer chain, as observed in the solvate [Pb(η-C 5 H 5 )·C 6 H 5 Me ] ∞ 1, and cyclisation into hexamers, as seen in the new hexagonal phase [Pb(η-C 5 H 5 ) 2 ] 6 2.

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Article information

DOI
https://doi.org/10.1039/A607561D
Article type
Paper

Chem. Commun., 1997, 109-110

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Solvent directed aggregation of a metallocene; structures of {[Pb(η-C5H5)2]3 ·C6H5Me}∞ and [Pb(η-C5H5)2]6

M. A. Beswick, C. Lopez-Casideo, M. A. Paver, P. R. Raithby, C. A. Russell, A. Steiner and D. S. Wright, Chem. Commun., 1997, 109 DOI: 10.1039/A607561D

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