Issue 22, 2002

Enantioselective epoxidation of olefins catalyzed by Mn (salen)/MCM-41 synthesized with a new anchoring method

Abstract

New immobilization of the chiral Mn(salen) complex through the complexation of manganese by oxygen atoms of the phenoxyl groups grafted on the surface of MCM-41 leads to a markedly higher ee than for the free complex.

Graphical abstract: Enantioselective epoxidation of olefins catalyzed by Mn (salen)/MCM-41 synthesized with a new anchoring method

Article information

Article type
Communication
Submitted
26 Jun 2002
Accepted
27 Sep 2002
First published
16 Oct 2002

Chem. Commun., 2002, 2696-2697

Enantioselective epoxidation of olefins catalyzed by Mn (salen)/MCM-41 synthesized with a new anchoring method

S. Xiang, Y. Zhang, Q. Xin and C. Li, Chem. Commun., 2002, 2696 DOI: 10.1039/B206104J

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