Issue 20, 2003
From the journal:

Organic & Biomolecular Chemistry

Construction of medium-ring oxacycloalkenones. Extension towards benzo-fused cyclic ethers

Frédéric Lecornuéa  and  Jean Ollivier*a  

* Corresponding authors

a Laboratoire des Carbocycles, UMR 8615, Institut de Chimie Moléculaire et des Matériaux d'Orsay Bât. 420, Université de Paris-Sud, 91405 ORSAY, France
E-mail: jollivie@icmo.u-psud.fr
Fax: +33 1 69 15 62 78
Tel: +33 1 69 15 72 52

Abstract

Application of the intramolecular Kulinkovich cyclopropanation of oxa-ω-alkenoic esters followed by Saegusa oxidation and dehydrohalogenation led to simple or benzo-fused oxacycloalkenones, basic structural elements in a wide range of naturally occurring compounds.

Graphical abstract: Construction of medium-ring oxacycloalkenones. Extension towards benzo-fused cyclic ethers

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Article information

DOI
https://doi.org/10.1039/B307289B
Article type
Paper
Submitted
25 Jun 2003
Accepted
03 Sep 2003
First published
23 Sep 2003

Org. Biomol. Chem., 2003,1, 3600-3604

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Construction of medium-ring oxacycloalkenones. Extension towards benzo-fused cyclic ethers

F. Lecornué and J. Ollivier, Org. Biomol. Chem., 2003, 1, 3600 DOI: 10.1039/B307289B

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