Issue 1, 2004
From the journal:

Chemical Communications

A novel, tandem construction of C–N and C–C bonds: facile and one-pot transformation of the Baylis–Hillman adducts into 2-benzazepines†

Deevi Basavaiah*a  and  Tummanapalli Satyanarayanaa  

* Corresponding authors

a School of Chemistry, University of Hyderabad, Hyderabad 500 046, India

Abstract

A novel reaction involving tandem construction of C–N and C–C bonds via the simultaneous Ritter and Houben–Hoesch reactions on Baylis–Hillman adducts leading to a convenient, one-pot synthesis of 2-benzazepine derivatives is described. A facile stereoselective transformation of the Baylis–Hillman adducts into (E)- and (Z)-allyl amides is also presented.

Graphical abstract: A novel, tandem construction of C–N and C–C bonds: facile and one-pot transformation of the Baylis–Hillman adducts into 2-benzazepines

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Article information

DOI
https://doi.org/10.1039/B310550D
Article type
Communication
Submitted
02 Sep 2003
Accepted
12 Nov 2003
First published
28 Nov 2003

Chem. Commun., 2004, 32-33

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A novel, tandem construction of C–N and C–C bonds: facile and one-pot transformation of the Baylis–Hillman adducts into 2-benzazepines

D. Basavaiah and T. Satyanarayana, Chem. Commun., 2004, 32 DOI: 10.1039/B310550D

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