Issue 17, 1998

New paradigms in cycloaddition face-selectivities: remarkable effect of remote substituents in singlet oxygen addition to hexacyclo[7.5.1.01,6.06,13.08,12.010,14]pentadeca-2,4-diene system

Abstract

Different modes of direct through-space interactions between remote substituents and an approaching reagent are indicated as important additional controlling factors of face selectivity in singlet oxygen cycloaddition to facially differentiated cyclohexa-1,3-dienes.

Article information

Article type
Paper

Chem. Commun., 1998, 1813-1814

New paradigms in cycloaddition face-selectivities: remarkable effect of remote substituents in singlet oxygen addition to hexacyclo[7.5.1.01,6.06,13.08,12.010,14]pentadeca-2,4-diene system

G. Mehta, R. Uma, M. N. Jagadeesh and J. Chandrasekhar, Chem. Commun., 1998, 1813 DOI: 10.1039/A804313B

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