Issue 15, 2003
From the journal:

Chemical Communications

Cyanide-bridged Fe(iii)–Co(ii) bis double zigzag chains with a slow relaxation of the magnetisation†

Luminita Marilena Toma,a   Rodrigue Lescouëzec,a   Francesc Lloret,a   Miguel Julve,*a   Jacqueline Vaissermannb  and  Michel Verdaguerb  

* Corresponding authors

a Departament de Química Inorgànica/Instituto de Ciencia Molecular, Facultat de Química de la Universitat de València, Avda. Dr. Moliner 50, 46100-Burjassot (València), Spain

b Laboratoire de Chimie Inorganique et Matériaux Moléculaires, Unité CNRS 7071, Université Pierre et Marie Curie, 4 Place Jussieu, Case 42, 75252 Paris Cedex 05, France

Abstract

Reaction of [FeIII(bipy)(CN)4]− with fully solvated MII cations [M = Co (1) and Mn (2)] produces the isostructural bis double zigzag chains [[FeIII(bipy)(CN)4]2MII(H2O)]·MeCN·½H2O; 1 exhibits intrachain ferromagnetic and interchain antiferromagnetic couplings, slow magnetic relaxation and hysteresis effects.

Graphical abstract: Cyanide-bridged Fe(iii)–Co(ii) bis double zigzag chains with a slow relaxation of the magnetisation

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Article information

DOI
https://doi.org/10.1039/B302182N
Article type
Communication
Submitted
24 Feb 2003
Accepted
20 May 2003
First published
27 Jun 2003

Chem. Commun., 2003, 1850-1851

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Cyanide-bridged Fe(III)–Co(II) bis double zigzag chains with a slow relaxation of the magnetisation

L. M. Toma, R. Lescouëzec, F. Lloret, M. Julve, J. Vaissermann and M. Verdaguer, Chem. Commun., 2003, 1850 DOI: 10.1039/B302182N

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