Issue 11, 2006

Facile assembly of a Cu9 amido complex: a new tripodal ligand design that promotes transition metal cluster formation

Abstract

A tripodal amido ligand with a central non-chelating phosphorus donor allows for the facile assembly of a pentane soluble organometallic copper cluster with a central copper atom surrounded by a nonplanar chain of eight copper atoms and two terminal amido–copper bonds.

Graphical abstract: Facile assembly of a Cu9 amido complex: a new tripodal ligand design that promotes transition metal cluster formation

Supplementary files

Article information

Article type
Communication
Submitted
09 Dec 2005
Accepted
26 Jan 2006
First published
10 Feb 2006

Chem. Commun., 2006, 1221-1223

Facile assembly of a Cu9 amido complex: a new tripodal ligand design that promotes transition metal cluster formation

A. L. Keen, M. Doster, H. Han and S. A. Johnson, Chem. Commun., 2006, 1221 DOI: 10.1039/B517531C

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