Issue 11, 2008
From the journal:

Chemical Communications

A three-dimensional metal–organic framework with a distorted Kagome related layer showing canted antiferromagnetic behaviour†

Partha Mahata,a   Diptiman Sen*b  and  Srinivasan Natarajan*a  

* Corresponding authors

a Framework Solids Laboratory, Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560 012, India
E-mail: snatarajan@sscu.iisc.ernet.in
Fax: +91-80-2360-1310

b Centre for High Energy Physics, Indian Institute of Science, Bangalore 560 012, India
E-mail: diptiman@cts.iisc.ernet.in

Abstract

Three-dimensional [Mn3{C6H3(COO)3}2] comprising two-dimensional –Mn–O–Mn– distorted Kagome layers, formed by two geometrically different hexa-coordinated Mn2+ ions, show less frustration and spin canted long range ordering possibly due to antisymmetric exchange.

Graphical abstract: A three-dimensional metal–organic framework with a distorted Kagome related layer showing canted antiferromagnetic behaviour

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Article information

DOI
https://doi.org/10.1039/B715314G
Article type
Communication
Submitted
05 Oct 2007
Accepted
14 Nov 2007
First published
22 Nov 2007

Chem. Commun., 2008, 1278-1280

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A three-dimensional metal–organic framework with a distorted Kagome related layer showing canted antiferromagnetic behaviour

P. Mahata, D. Sen and S. Natarajan, Chem. Commun., 2008, 1278 DOI: 10.1039/B715314G

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