Issue 19, 2010
From the journal:

Chemical Communications

Nickel-catalyzed Tishchenko reactionvia hetero-nickelacycles by oxidative cyclization of aldehydes with nickel(0) complex†

Sensuke Ogoshi,*a   Yoichi Hoshimotoa  and  Masato Ohashiab  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, Japan

b Center for Atomic and Molecular Technologies, Osaka University, Suita, Osaka 565-0871, Japan
E-mail: ogoshi@chem.eng.osaka-u.ac.jp

Abstract

A Ni(0)-catalyzed Tishchenko reaction which can be applied to a variety of aliphatic aldehydes (1°, 2°, 3°) and aromatic aldehydes was developed. The reaction might proceed via a hetero-nickelacycle intermediate.

Graphical abstract: Nickel-catalyzed Tishchenko reaction via hetero-nickelacycles by oxidative cyclization of aldehydes with nickel(0) complex

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Article information

DOI
https://doi.org/10.1039/B926866A
Article type
Communication
Submitted
21 Dec 2009
Accepted
22 Feb 2010
First published
25 Mar 2010

Chem. Commun., 2010,46, 3354-3356

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Nickel-catalyzed Tishchenko reaction via hetero-nickelacycles by oxidative cyclization of aldehydes with nickel(0) complex

S. Ogoshi, Y. Hoshimoto and M. Ohashi, Chem. Commun., 2010, 46, 3354 DOI: 10.1039/B926866A

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