Issue 9, 2000
From the journal:

Journal of the Chemical Society, Dalton Transactions

Ascorbateoxidation leading to the formation of a catalytically active oxalato bridged dicopper(II) complex as a model for dopamine β-hydroxylase

Anitha M. Thomas,a   Gagan C. Mandal,a   Satish K. Tiwary,a   Rakesh K. Ratha  and  Akhil R. Chakravarty*a  

* Corresponding authors

a Department of Inorganic & Physical Chemistry, Indian Institute of Science, Bangalore, India
E-mail: arc@ipc.iisc.ernet.in

Abstract

A dicopper(II) complex [Cu2(bpy)2(μ-ox)]X2 (X = ClO4−, PF6−; ox = C2O42−) has been found to be catalytically active in the oxidation of ascorbic acid by dioxygen involving a copper(I) intermediate species and the process is also effective in the presence of benzylamine to form benzaldehyde.

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Article information

DOI
https://doi.org/10.1039/B001055N
Article type
Communication
Submitted
08 Feb 2000
Accepted
20 Mar 2000
First published
05 Apr 2000

J. Chem. Soc., Dalton Trans., 2000, 1395-1396

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Ascorbate oxidation leading to the formation of a catalytically active oxalato bridged dicopper(II) complex as a model for dopamine β-hydroxylase

A. M. Thomas, G. C. Mandal, S. K. Tiwary, R. K. Rath and A. R. Chakravarty, J. Chem. Soc., Dalton Trans., 2000, 1395 DOI: 10.1039/B001055N

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