Issue 32, 2009
From the journal:

Dalton Transactions

Transformation of hydroxylamide into hydrazide units in the coordination spheres of group 4 metals†

Alexander Willner,a   Beate Neumann,a   Hans-Georg Stammlera  and  Norbert W. Mitzel*a  

* Corresponding authors

a Lehrstuhl für Anorganische Chemie und Strukturchemie, Universitätsstraße 25, Bielefeld, Germany
E-mail: mitzel@uni-bielefeld.de
Fax: +49 521 106 6026
Tel: +49 521 106 6182

Abstract

Hydroxylamine units, bonded via their oxygen atom to a cyclo-pentadienyldimethylsilyl group are transformed into siloxy ligands and hydrazide units by the reaction with tetrakis(dimethylamido)-titanium and -zirconium by the same reaction principle but resulting in different aggregates of the products.

Graphical abstract: Transformation of hydroxylamide into hydrazide units in the coordination spheres of group 4 metals

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Article information

DOI
https://doi.org/10.1039/B908176C
Article type
Communication
Submitted
23 Apr 2009
Accepted
15 Jun 2009
First published
23 Jun 2009

Dalton Trans., 2009, 6280-6282

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Transformation of hydroxylamide into hydrazide units in the coordination spheres of group 4 metals

A. Willner, B. Neumann, H. Stammler and N. W. Mitzel, Dalton Trans., 2009, 6280 DOI: 10.1039/B908176C

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