Issue 12, 2005
From the journal:

New Journal of Chemistry

Molecular tectonics: coordination networks based on porphyrins bearing pyridine N-oxide groups as coordinating sites†

Emmanuel Deiters,a   Véronique Bulach,*a   Nathalie Kyritsakasa  and  Mir Wais Hosseini*a  

* Corresponding authors

a Laboratoire de Chimie de Coordination Organique, UMR CNRS 7140, Université Louis Pasteur, France
E-mail: hosseini@chimie.u-strasbg.fr, bulach@chimie.u-strasbg.fr

Abstract

The combination of the two positional isomers 1 and 2, porphyrin backbones bearing two pyridine N-oxide groups (PNO), with Zn(II) cations leads to 1-Zn and 2-Zn self-complementary tectons which generate in the crystalline phase analogous 1-D zigzag type coordination networks with different metrics. In both cases, only one PNO group bridges the consecutive tecton through coordination to the Zn atom which adopts the square based pyramidal geometry.

Graphical abstract: Molecular tectonics: coordination networks based on porphyrins bearing pyridine N-oxide groups as coordinating sites

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Article information

DOI
https://doi.org/10.1039/B511049C
Article type
Paper
Submitted
02 Aug 2005
Accepted
15 Sep 2005
First published
05 Oct 2005

New J. Chem., 2005,29, 1508-1513

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Molecular tectonics: coordination networks based on porphyrins bearing pyridine N-oxide groups as coordinating sites

E. Deiters, V. Bulach, N. Kyritsakas and M. W. Hosseini, New J. Chem., 2005, 29, 1508 DOI: 10.1039/B511049C

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