Issue 4, 2000
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

New copper(I) and iron(II) complexes for atom transfer radical macrocyclisation reactions

Floryan De Campo,a   Dominique Lastécouèresa  and  Jean-Baptiste Verlhac*a  

* Corresponding authors

a Laboratoire de Chimie Organique et Organométallique (UMR 5802 CNRS), Université Bordeaux I, 351 cours de la Libération, Talence Cedex, France
E-mail: j-b.verlhac@lcoo.u-bordeaux.fr

Abstract

New Cu(I) and Fe(II) complexes have been synthesized and proved to be efficient catalysts for atom transfer radical addition (ATRA) reactions. The catalytic activity was found to be greater than existing atom transfer systems based upon CuCl(bipyridine) or RuCl2(PPh3)3, for example. The addition of a reducing agent considerably improved the efficiency of the usual procedures.

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Article information

DOI
https://doi.org/10.1039/A908245J
Article type
Paper
Submitted
14 Oct 1999
Accepted
23 Dec 1999
First published
15 Feb 2000

J. Chem. Soc., Perkin Trans. 1, 2000, 575-580

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New copper(I) and iron(II) complexes for atom transfer radical macrocyclisation reactions

F. De Campo, D. Lastécouères and J. Verlhac, J. Chem. Soc., Perkin Trans. 1, 2000, 575 DOI: 10.1039/A908245J

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