Issue 12, 1981
From the journal:

Journal of the Chemical Society, Chemical Communications

Second-sphere co-ordination of neutral and cationic transition metal complexes by crown ethers

Howard M. Colquhoun  and  J. Fraser Stoddart  

Abstract

The[ammine(η5-cyclopentadienyl) dicarbonyl-iron(II)] cation and the neutral complex amminepentacarbonyltungsten(0), form 1:1 adducts in solution with 18-crown-6 and dibenzo-18-crown-6 by virtue of hydrogen bonding between the ammine ligand in the transition metal complex and oxygen atoms of the crown ether; a crystalline adduct, [W(CO)5NH3 dibenzo-18-crown-6], has been isolated as a benzene solvate.

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Article information

DOI
https://doi.org/10.1039/C39810000612
Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 612-613

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Second-sphere co-ordination of neutral and cationic transition metal complexes by crown ethers

H. M. Colquhoun and J. F. Stoddart, J. Chem. Soc., Chem. Commun., 1981, 612 DOI: 10.1039/C39810000612

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