The structure of LiBiO2, determined by powder neutron diffraction, contains adjacent rocksalt-related BiO layers similar to those found in superconducting phases, but the simpler composition has allowed reliable determination of the Bi3+ co-ordination (pyramidal with Bi–O bonds of 2.038, 2.096, and 2.130 Å).
C. Greaves and S. M. A. Katib, J. Chem. Soc., Chem. Commun., 1989, 902 DOI: 10.1039/C39890000902
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