Issue 23, 1990
From the journal:

Journal of the Chemical Society, Chemical Communications

Stepwise addition of PtPPh3 fragments on [Re2(CO)10]. X-Ray crystal structures of the complexes [Re2Ptn(µ-CO)2n(CO)10 – 2n(PPh3)n](n= 2, 3), the first examples of tetra-and penta-nuclear rhenium–platinum mixed-metal clusters

Gianfranco Ciani,   Massimo Moret,   Angelo Sironi,   Tiziana Beringhelli,   Giuseppe D'Alfonso  and  Roberto Della Pergola  

Abstract

Up to three PtPPh3 fragments, originating from [Pt(PPh3)2(C2H4)], can be added to [Re2(CO)10] affording [Re2Ptn(µ-CO)2n(CO)10 – 2n(PPh3)n](n= 1, 2, 3) mixed metal clusters, with structures based on electron short (46 valence electrons) Re2Pt triangles condensed on the Re–Re hinge.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C39900001668
Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 1668-1670

Permissions

Request permissions

Stepwise addition of PtPPh3 fragments on [Re2(CO)10]. X-Ray crystal structures of the complexes [Re2Ptn(µ-CO)2n(CO)10 – 2n(PPh3)n](n= 2, 3), the first examples of tetra-and penta-nuclear rhenium–platinum mixed-metal clusters

G. Ciani, M. Moret, A. Sironi, T. Beringhelli, G. D'Alfonso and R. D. Pergola, J. Chem. Soc., Chem. Commun., 1990, 1668 DOI: 10.1039/C39900001668

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements