Issue 6, 1983
From the journal:

Journal of the Chemical Society, Dalton Transactions

Trimeric thioformaldehyde as a ligand: preparation and crystal structure of [Ag2{(CH2S)3}5][AsF6]2·SO2

Herbert W. Roesky,   Hartmut Hofmann,   Peter G. Jones,   Waltraud Pinkert  and  George M. Sheldrick  

Abstract

The reaction of trimeric thioformaldehyde with AgAsF6 in liquid SO2 leads to the compound [Ag2{(CH2S)3}5][AsF6]2·SO2, which was characterised by X-ray structure determination [space group Pbca, with a= 16.286(3), b= 28.487(5), c= 18.118(3)Å, and Z= 8; R= 0.061 for 5 150 unique observed reflections]. The isolated canons, of the form L2AgLAgL2(L = ligand), display irregular co-ordination geometry at silver; one silver is co-ordinated by four sulphurs from three ligands, the other by five sulphurs from three ligands.

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Article information

DOI
https://doi.org/10.1039/DT9830001215
Article type
Paper

J. Chem. Soc., Dalton Trans., 1983, 1215-1216

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Trimeric thioformaldehyde as a ligand: preparation and crystal structure of [Ag2{(CH2S)3}5][AsF6]2·SO2

H. W. Roesky, H. Hofmann, P. G. Jones, W. Pinkert and G. M. Sheldrick, J. Chem. Soc., Dalton Trans., 1983, 1215 DOI: 10.1039/DT9830001215

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