Issue 11, 1994
From the journal:

Journal of the Chemical Society, Dalton Transactions

Mono- and bi-dentate phosphaalkene ligands: structures of their copper(I) chloride complexes

Abdelaziz Jouaiti,   Michel Geoffroy  and  Gérald Bernardinelli  

Abstract

While the reaction of the monophosphaalkene [(2,4,6-tri-tert-butylphenyl)phosphanediylmethyl]-benzene (L2) with copper(I) chloride led to a dimeric complex [Cu2Cl2L22(NCMe)2]1, use of the diphosphaalkene 1,3-bis[(2,4,6-tri-tert-butylphenyl)phosphanediylmethyl]benzene (L1) gave rise to a tetrameric complex [Cu4Cl4L12]·3EtOH 2. The crystal structures of the complexes have been determined and indicate that 1 is a centrosymmetric dimer with tetrahedrally co-ordinated copper(I) centres, whereas 2 adopts a ‘cubane-like’ structure with pairs of copper atoms bridged by different L1 units.

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Article information

DOI
https://doi.org/10.1039/DT9940001685
Article type
Paper

J. Chem. Soc., Dalton Trans., 1994, 1685-1688

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Mono- and bi-dentate phosphaalkene ligands: structures of their copper(I) chloride complexes

A. Jouaiti, M. Geoffroy and G. Bernardinelli, J. Chem. Soc., Dalton Trans., 1994, 1685 DOI: 10.1039/DT9940001685

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