Issue 5, 1991

New perovskite phases in the systems Li2O–(Nb2O5, Ta2O5)–ZrO2

Abstract

Two new orthorhombic perovskite phases of formula, Li0.704 –xZr0.074 + 4x Ta1 – 3xO3, where 0.08 < x < 0.15 and Li0.774 –xZr0.057+4xNb1 – 3xO3, where 0 < x < 0.15, have been synthesized. Their stoichiometries were determined as part of a phase-diagram study of the systems Li2O–Nb2O5–ZrO2 and Li2O–Ta2O5–ZrO2. In addition to these new phases, extensive solid solutions based on Zr-doped LiNbO3, LiNb3O8, LiTaO3 and LiTa3O8 have been prepared.

Article information

Article type
Paper

J. Mater. Chem., 1991,1, 747-749

New perovskite phases in the systems Li2O–(Nb2O5, Ta2O5)–ZrO2

M. E. Villafuerte-Castrejon, C. Kuhliger, R. Ovando, R. I. Smith and A. R. West, J. Mater. Chem., 1991, 1, 747 DOI: 10.1039/JM9910100747

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