Issue 8, 1996
From the journal:

Journal of Materials Chemistry

Synthesis and crystal structures of ‘Li 1.8K0.9M0.75Zr2.25O6.6’(M = Cu, Mg): a family of novel rocksalt–perovskite intergrowth phases

Glenn C. Mather,   R. Alan Howie,   Bénédicte Thiebaut,   Eric E. Lachowski,   Desmond Eadon,   Tim Hyde  and  Anthony R. West  

Abstract

The new phases, Li 1.8K 0.9M 0.75Zr2.25O6.6(M = Cu, Mg), have a novel rocksalt-perovskite intergrowth structure, with space group I4/mmm; a=; 4.1630(1), c= 18.1086(7)Å, Z = 2 for M = Cu and a= 4.1739(3), c= 17.971(2)Å for M = Mg, formed from ‘KZrO3’ perovskite units and rocksalt units ‘Li2M0.75Zr1.25O3.75’. A weak incommensurate supercell, not detected by X-ray diffraction, was characterised by electron diffraction; the supercell is parallel to [301] of the tetragonal subcell.

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Article information

DOI
https://doi.org/10.1039/JM9960601379
Article type
Paper

J. Mater. Chem., 1996,6, 1379-1383

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Synthesis and crystal structures of ‘Li 1.8K0.9M0.75Zr2.25O6.6’(M = Cu, Mg): a family of novel rocksalt–perovskite intergrowth phases

G. C. Mather, R. A. Howie, B. Thiebaut, E. E. Lachowski, D. Eadon, T. Hyde and A. R. West, J. Mater. Chem., 1996, 6, 1379 DOI: 10.1039/JM9960601379

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