Alkyl radicals, produced from alkyl bromides and iodides, react smoothly with triphenylprop-2-ynylstannane to provide terminal allenes; this new reaction has been applied to a simple and stereospecific synthesis of the naturally occurring allenic amino-acid, S-2-aminohexa-4,5-dienoic acid.
J. E. Baldwin, R. M. Adlington and A. Basak, J. Chem. Soc., Chem. Commun., 1984, 1284 DOI: 10.1039/C39840001284
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