Reductive and non-reductive insertions of silicon atoms into carbaborane cages: synthesis and structure of a carbaborane analogue of bis(cyclopentadienyl)silicon

Narayan S. Hosmane; Patrice de Meester; Upali Siriwardane; M. Safiqual Islam; Shirley S. C. Chu

doi:10.1039/C39860001421

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Reductive and non-reductive insertions of silicon atoms into carbaborane cages: synthesis and structure of a carbaborane analogue of bis(cyclopentadienyl)silicon

Narayan S. Hosmane, Patrice de Meester, Upali Siriwardane, M. Safiqual Islam and Shirley S. C. Chu

Abstract

The silacarbaboranes [(Me₃Si)₂C₂B₄H₄]Si^II(1) and [(Me₃Si)₂C₂B₄H₄]₂Si^IV(2) have been prepared and the structure of (2) has been determined by X-ray crystallography.

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DOI: https://doi.org/10.1039/C39860001421
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1986, 1421-1422

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Reductive and non-reductive insertions of silicon atoms into carbaborane cages: synthesis and structure of a carbaborane analogue of bis(cyclopentadienyl)silicon

N. S. Hosmane, P. de Meester, U. Siriwardane, M. S. Islam and S. S. C. Chu, J. Chem. Soc., Chem. Commun., 1986, 1421 DOI: 10.1039/C39860001421

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Journal of the Chemical Society, Chemical Communications

Reductive and non-reductive insertions of silicon atoms into carbaborane cages: synthesis and structure of a carbaborane analogue of bis(cyclopentadienyl)silicon

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Reductive and non-reductive insertions of silicon atoms into carbaborane cages: synthesis and structure of a carbaborane analogue of bis(cyclopentadienyl)silicon

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