Issue 20, 1994
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and structure of the distorted octahedral palladium(II) complex [Pd(tmpp)2][BF4]2[tmpp = tris(2,4,6-trimethoxyphenyl)phosphine]

Kim R. Dunbar  and  Jui-Sui Sun  

Abstract

The brick-red PdII complex [Pd(tmpp)2][BF4]2 is isolated from the reaction of [Pd(NCCH3)4][BF4]2 and tmpp (tris(2,4,6-trimethoxyphenyl)phosphine)(2 equiv.) in acetone at –44 °C; the new phosphine compound constitutes a rare example of a distored octahedral PdII compound and exhibits the shortest Pd–Lax distances reported to date for six-coordinate PdII complexes.

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Article information

DOI
https://doi.org/10.1039/C39940002387
Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 2387-2388

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Synthesis and structure of the distorted octahedral palladium(II) complex [Pd(tmpp)2][BF4]2[tmpp = tris(2,4,6-trimethoxyphenyl)phosphine]

K. R. Dunbar and J. Sun, J. Chem. Soc., Chem. Commun., 1994, 2387 DOI: 10.1039/C39940002387

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