Issue 2, 2003

Increasing the crystallisation temperature to access new spin clusters: conversion of [Ni8(cit)6(OH)2(H2O)2]10− to [Ni8(cit)6(OH)2]10−

Abstract

The role of temperature in the formation of high nuclearity nickel(II) citrate spin clusters is explored, revealing how changes in structure and hence magnetic properties can be triggered through desolvation and ligand reorganisation.

Graphical abstract: Increasing the crystallisation temperature to access new spin clusters: conversion of [Ni8(cit)6(OH)2(H2O)2]10− to [Ni8(cit)6(OH)2]10−

Supplementary files

Article information

Article type
Communication
Submitted
23 Oct 2002
Accepted
21 Nov 2002
First published
10 Dec 2002

Chem. Commun., 2003, 230-231

Increasing the crystallisation temperature to access new spin clusters: conversion of [Ni8(cit)6(OH)2(H2O)2]10− to [Ni8(cit)6(OH)2]10−

M. Murrie, D. Biner, H. Stœckli-Evans and H. U. Güdel, Chem. Commun., 2003, 230 DOI: 10.1039/B210327C

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