Issue 6, 2003
From the journal:

Chemical Communications

Cooperative effects in the complexation of anions and Lewis bases by a heteronuclear bifunctional Lewis acid†

James D. Hoefelmeyera  and  François P. Gabbaï*a  

* Corresponding authors

a Chemistry Department, Texas A&M University, 3255 TAMU, College Station, Texas, USA
E-mail: francois@tamu.edu
Fax: +1 979 8454719
Tel: +1 979 862 2070

Abstract

As shown by the complexation of electron-rich substrates to the heteronuclear bifunctional Lewis acid bis(μ-1,8-naphthalenediyl)(μ-chloride)methyltin-chlorogallium (1), the primary Lewis acidic site of this molecule is the triorganotin chloride moiety whose electron deficiency is enhanced through partial abstraction of its chloride ligand by the neighbouring gallium centre.

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Article information

DOI
https://doi.org/10.1039/B212127A
Article type
Communication
Submitted
05 Dec 2002
Accepted
28 Jan 2003
First published
14 Feb 2003

Chem. Commun., 2003, 712-713

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Cooperative effects in the complexation of anions and Lewis bases by a heteronuclear bifunctional Lewis acid

J. D. Hoefelmeyer and F. P. Gabbaï, Chem. Commun., 2003, 712 DOI: 10.1039/B212127A

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