Issue 6, 2007
From the journal:

Chemical Communications

Chemistry of enediynyl azides: activation through a novel pathway†

Amit Basak,*a   Sandip K. Roy,a   Sanket Das,a   Amrita B. Hazra,a   Subhash C. Ghosha  and  Shailendra Jhab  

* Corresponding authors

a Bioorganic Laboratory, Department of Chemistry, Indian Institute of Technology, Kharagpur, India
E-mail: absk@chem.iitkgp.ernet.in
Fax: 91 3222 282252
Tel: 91 3222 283300

b Department of Chemistry, Jadvapur University, Kolkata, India

Abstract

The spontaneous activation of a nonaromatic enediynyl azide under ambient conditions has been demonstrated. The aromatic enediyne followed the expected cycloaddition with the alkene in the neighbouring arm to form a stable bridged bicyclic enediyne.

Graphical abstract: Chemistry of enediynyl azides: activation through a novel pathway

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Article information

DOI
https://doi.org/10.1039/B612114D
Article type
Communication
Submitted
22 Aug 2006
Accepted
02 Oct 2006
First published
01 Nov 2006

Chem. Commun., 2007, 622-624

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Chemistry of enediynyl azides: activation through a novel pathway

A. Basak, S. K. Roy, S. Das, A. B. Hazra, S. C. Ghosh and S. Jha, Chem. Commun., 2007, 622 DOI: 10.1039/B612114D

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